Functionalization of P4 in the coordination sphere of coinage metal cations.
نویسندگان
چکیده
Selective functionalization of white phosphorus is achieved by addition of ArLi to unique cationic coinage metal η(2)-P4 complexes. This novel approach allows controlled P-C bond formation using the bulky DmpLi (Dmp = 2,6-Mes2C6H3) and the unencumbered MesLi, giving sterically diverse doubly complexed RP4 butterfly derivatives in a single step.
منابع مشابه
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عنوان ژورنال:
- Chemical communications
دوره 52 16 شماره
صفحات -
تاریخ انتشار 2016